The structure and bonding of Au₂₅(SR)₁₈ nanoclusters from EXAFS: The interplay of metallic and molecular behavior

Keyphrases

• Ab Initio Calculations 20%
• Au Shell 20%
• Au13 20%
• Au25 100%
• Au25 Nanoclusters 20%
• Catalytic Mechanism 20%
• Changes in Structures 20%
• Electronic Properties 20%
• Extended X-ray Absorption Fine Structure (EXAFS) 100%
• Fitting Approach 20%
• Gold Thiosulfate 60%
• Local Density of States 20%
• Low Temperature 40%
• Metallic Behavior 100%
• Metallic Interactions 20%
• Molecular Behavior 100%
• Molecular Interactions 20%
• Nanoclusters 100%
• Nanomaterials 40%
• Recent Advances 20%
• Solvation 40%
• Solvation Environment 20%
• Structural Change 20%
• Structure Fitting 20%
• Structure Simulation 20%
• Thiolate 20%
• X-ray Absorption Fine Structure Analysis 20%

Material Science

• Ab Initio Calculation 20%
• Crystallography 20%
• Density 20%
• Electronic Property 20%
• Extended X-Ray Absorption Fine Structure 100%
• Nanoclusters 100%
• Nanocrystalline Material 40%
• Solvation 60%

Chemistry

• Ab Initio Calculation 33%
• Density of State 33%
• Electronic Property 33%
• Nanomaterial 66%
• Solvation 100%
• Structure 66%